Human communication includes information, opinions and reactions. Reactions are often captured by the affective-messages in written as well as verbal communications. While there has been work in affect modeling and to some extent affective content generation, the area of affective word distributions is not well studied. Synsets and lexica capture semantic relationships across words. These models, however, lack in encoding affective or emotional word interpretations. Our proposed model, Aff2Vec, provides a method for enriched word embeddings that are representative of affective interpretations of words. Aff2Vec outperforms the state-of-the-art in intrinsic word-similarity tasks. Further, the use of Aff2Vec representations outperforms baseline embeddings in downstream natural language understanding tasks including sentiment analysis, personality detection, and frustration prediction.